Bu öğeden alıntı yapmak, öğeye bağlanmak için bu tanımlayıcıyı kullanınız: http://hdl.handle.net/11452/24093
Başlık: One-dimensional silver(I) 5,5-diethylbarbiturato coordination polymers with N-piperidineethanol and 1,3-bis(4-piperidyl)propane: Syntheses, crystal structures, spectroscopic and thermal properties
Yazarlar: Büyükgüngör, Orhan
Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü.
0000-0002-2849-3332
Yılmaz, Veysel Turan
Soyer, Eda
L-7238-2018
7006269202
32267686800
Anahtar kelimeler: 5,5-Diethylbarbiturate
N-Piperidineethanol
1,3-Bis(4-piperidyl)propane
Coordination polymers
Silver(I)
Antimicrobial activity
Complexes
Copper(II)
Ligands
Zinc
Chemistry
Crystallography
Yayın Tarihi: 1-Şub-2010
Yayıncı: Pergamon-Elsevier Science
Atıf: Yılmaz, V. T. vd. (2010). "One-dimensional silver(I) 5,5-diethylbarbiturato coordination polymers with N-piperidineethanol and 1,3-bis(4-piperidyl)propane: Syntheses, crystal structures, spectroscopic and thermal properties". Polyhedron, 29(2), 920-924.
Özet: Two new coordination polymers, [Ag(2)(barb)(pipet)](n) (1) and {Na(3)[Ag(2)(barb)(2)](pippr)center dot 2H(2)O}(n) (2) (where H(2)barb, pipet and Hpippr are 5,5-diethylbarbituric acid, N-piperidineethanol and 1,3-bis(4-piperidyl)propane, respectively) have been synthesized and characterized by elemental analysis, IR, thermal analysis and X-ray single-crystal diffraction techniques. Silver(I) ions in complexes 1 and 2 are bridged by barb dianions, leading to one-dimensional coordination polymers. In 1, the barb ligand acts as a tetradentate bridging ligand, while in 2 as a bidendate bridging ligand. The pipet ligand behaves as a bidentate chelating donor, whereas the pippr anion is not involved in coordination and remains as a counter-ion. The one-dimensional chains of 1 and 2 are further extended into supramolecular networks. Spectral and thermal analysis data for 1 and 2 are in agreement with the crystal structures.
URI: https://doi.org/10.1016/j.poly.2009.10.029
https://www.sciencedirect.com/science/article/pii/S0277538709006949
http://hdl.handle.net/11452/24093
ISSN: 0277-5387
Koleksiyonlarda Görünür:Scopus
Web of Science

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