Please use this identifier to cite or link to this item:
http://hdl.handle.net/11452/23614
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gümüş, Sedat | - |
dc.date.accessioned | 2021-12-24T12:44:07Z | - |
dc.date.available | 2021-12-24T12:44:07Z | - |
dc.date.issued | 2011-09 | - |
dc.identifier.citation | Güney, E. vd. (2011) ''Synthesis, experimental and theoretical characterization of palladium(II) and platinum(II) saccharinate complexes with 2-(2-pyridyl)benzimidazole''. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 79(5), 1171-1178. | en_US |
dc.identifier.issn | 1386-1425 | - |
dc.identifier.issn | 1873-3557 | - |
dc.identifier.uri | https://doi.org/10.1016/j.saa.2011.04.038 | - |
dc.identifier.uri | https://www.sciencedirect.com/science/article/pii/S138614251100285X | - |
dc.identifier.uri | http://hdl.handle.net/11452/23614 | - |
dc.description.abstract | New palladium(II) and platinum(II) complexes of saccharinate (sac) with 2-(2-pyridyl)benzimidazole (pybim) have been synthesized and characterized by elemental analysis and spectroscopic techniques. From the experimental studies, these complexes were formulated as [Pd(pybim)(sac)(2)] (1), and [Pt(pybim)(sac)(2)]center dot 4H(2)O (2). The ground-state geometries of both complexes were optimized using density functional theory (DFT) methods at the B3LYP level. A bidentate pybim ligand together with two N-coordinated sac ligands form the square-planar MN4 coordination geometry around the palladium(II) and platinum(II) ions. The calculated IR and UV-vis spectral data have been correlated to the experimental results. Thermal analysis data support the molecular structures of both complexes. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Pergamon-Elsevier Science | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Spectroscopy | en_US |
dc.subject | Saccharinate | en_US |
dc.subject | 2-(2-Pyridyl)benzimidazole | en_US |
dc.subject | Palladium(II) | en_US |
dc.subject | Platinum(II) | en_US |
dc.subject | DFT | en_US |
dc.subject | PT(II) | en_US |
dc.subject | ZINC(II) | en_US |
dc.subject | Vibrational frequencies | en_US |
dc.subject | Crystal-structures | en_US |
dc.subject | Ligands | en_US |
dc.subject | Benzimidazole | en_US |
dc.subject | Fluorescent | en_US |
dc.subject | Chemistry | en_US |
dc.subject | Polymers | en_US |
dc.subject | Density functional theory | en_US |
dc.subject | Ligands | en_US |
dc.subject | Platinum | en_US |
dc.subject | Platinum compounds | en_US |
dc.subject | Spectroscopic analysis | en_US |
dc.subject | Thermoanalysis | en_US |
dc.subject | Benzimidazoles | en_US |
dc.subject | Coordination geometry | en_US |
dc.subject | Data support | en_US |
dc.subject | Density functional theory methods | en_US |
dc.subject | Experimental studies | en_US |
dc.subject | Ground state geometry | en_US |
dc.subject | Saccharinate | en_US |
dc.subject | Spectral data | en_US |
dc.subject | Spectroscopic technique | en_US |
dc.subject | Palladium compounds | en_US |
dc.subject.mesh | Benzimidazoles | en_US |
dc.subject.mesh | Crystallography, X-ray | en_US |
dc.subject.mesh | Magnetic resonance spectroscopy | en_US |
dc.subject.mesh | Models, molecular | en_US |
dc.subject.mesh | Models, theoretical | en_US |
dc.subject.mesh | Molecular structure | en_US |
dc.subject.mesh | Organometallic compounds | en_US |
dc.subject.mesh | Palladium | en_US |
dc.subject.mesh | Platinum | en_US |
dc.subject.mesh | Spectrophotometry, infrared | en_US |
dc.title | Synthesis, experimental and theoretical characterization of palladium(II) and platinum(II) saccharinate complexes with 2-(2-pyridyl)benzimidazole | en_US |
dc.type | Article | en_US |
dc.identifier.wos | 000293363000047 | tr_TR |
dc.identifier.scopus | 2-s2.0-79960266565 | tr_TR |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi | tr_TR |
dc.contributor.department | Uludağ Üniversitesi/Fen-Edebiyat Fakültesi/Kimya Bölümü. | tr_TR |
dc.contributor.orcid | 0000-0002-2849-3332 | tr_TR |
dc.identifier.startpage | 1171 | tr_TR |
dc.identifier.endpage | 1178 | tr_TR |
dc.identifier.volume | 79 | tr_TR |
dc.identifier.issue | 5 | tr_TR |
dc.relation.journal | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy | en_US |
dc.contributor.buuauthor | Güney, Emel | - |
dc.contributor.buuauthor | Kaya, Yunus | - |
dc.contributor.buuauthor | Yılmaz, Veysel T. | - |
dc.contributor.researcherid | L-7238-2018 | tr_TR |
dc.relation.collaboration | Yurt içi | tr_TR |
dc.identifier.pubmed | 21665528 | tr_TR |
dc.subject.wos | Spectroscopy | en_US |
dc.indexed.wos | SCIE | en_US |
dc.indexed.scopus | Scopus | en_US |
dc.indexed.pubmed | Pubmed | en_US |
dc.wos.quartile | Q2 | en_US |
dc.contributor.scopusid | 25027291500 | tr_TR |
dc.contributor.scopusid | 35181446100 | tr_TR |
dc.contributor.scopusid | 7006269202 | tr_TR |
dc.subject.scopus | Benzisothiazole; Palladium; 2-Phenylpyridine | en_US |
dc.subject.emtree | 2 (2' pyridyl)benzimidazole | en_US |
dc.subject.emtree | 2-(2'-pyridyl)benzimidazole | en_US |
dc.subject.emtree | Benzimidazole derivative | en_US |
dc.subject.emtree | Organometallic compound | en_US |
dc.subject.emtree | Palladium | en_US |
dc.subject.emtree | Platinum | en_US |
dc.subject.emtree | Article | en_US |
dc.subject.emtree | Chemical structure | en_US |
dc.subject.emtree | Chemistry | en_US |
dc.subject.emtree | Infrared spectrophotometry | en_US |
dc.subject.emtree | Metabolism | en_US |
dc.subject.emtree | Nuclear magnetic resonance spectroscopy | en_US |
dc.subject.emtree | Synthesis | en_US |
dc.subject.emtree | Theoretical model | en_US |
dc.subject.emtree | X ray crystallography | en_US |
Appears in Collections: | Scopus Web of Science |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.